Sandmeier, Tobias; Goetzke, F. Wieland; Krautwald, Simon; Carreira, Erick M. published the article 《Iridium-catalyzed enantioselective allylic substitution with aqueous solutions of nucleophiles》. Keywords: iridium catalyzed enantioselective allylic substitution aqueous solution nucleophile.They researched the compound: 2-Bromomethyl-1,3-dioxolane( cas:4360-63-8 ).Product Details of 4360-63-8. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:4360-63-8) here.
The iridium-catalyzed asym. allylic substitution under biphasic conditions is reported. This approach allows the use of various unstable and/or volatile nucleophiles including hydrazines, methylamine, t-Bu hydroperoxide, N-hydroxylamine, α-chloroacetaldehyde and glutaraldehyde. This transformation provides rapid access to a broad range of products from simple starting materials in good yields and up to >99% ee and 20:1 d.r.. Addnl., these products can be elaborated efficiently into a diverse set of cyclic and acyclic compounds, bearing up to four stereocenters.
There is still a lot of research devoted to this compound(SMILES：BrCC1OCCO1)Product Details of 4360-63-8, and with the development of science, more effects of this compound(4360-63-8) can be discovered.
Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem