As a society publisher, everything we do is to support the scientific community – so you can trust us to always act in your best interests, and get your work the international recognition that it deserves. Quality Control of 4-(Hydroxymethyl)-5-methyl-1,3-dioxol-2-one91526-18-0, Name is 4-(Hydroxymethyl)-5-methyl-1,3-dioxol-2-one, SMILES is CC1=C(CO)OC(=O)O1, belongs to dioxole compound. In a article, author is Forsythe, JS, introduce new discover of the category.
The radiation chemistry of the copolymer of tetrafluoroethylene and 2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole (Teflon AF(R)) was investigated using gamma-irradiation under vacuum. Two types of resin were studied which differed in dioxole content; AF1600 65 mol% dioxole and AF2400 87 mol% dioxole. The cyclic fluoroplastic was found to undergo predominant main chain scission upon radiolysis, both above and below the glass transition temperature, which was characterised by a decrease in the glass transition temperature. FTIR analysis showed the formation of new carboxylate end groups as well as terminal unsaturation. Both CF . and CF2., radicals were identified using Electron Spin Resonance upon gamma-radiolysis and subsequent thermal annealing. The G-value for radical production at 77 K, G(R), was 1.6 for both resins. (C) 1998 Elsevier Science Ltd. All rights reserved.
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Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem