Category: 707-61-9

Related Products of 707-61-9. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, is researched, Molecular C11H13OP, CAS is 707-61-9, about Biphilic Organophosphorus-Catalyzed Intramolecular Csp2-H Amination: Evidence for a Nitrenoid in Catalytic Cadogan Cyclizations. Author is Nykaza, Trevor V.; Ramirez, Antonio; Harrison, Tyler S.; Luzung, Michael R.; Radosevich, Alexander T..

A small-ring phosphacycloalkane (1,2,2,3,4,4-hexamethylphosphetane) (I) catalyzes intramol. C-N bond forming heterocyclization of o-nitrobiaryls and o-nitrostyrenes in the presence of a hydrosilane terminal reductant. The method provides scalable access to diverse carbazole and indole compounds under operationally trivial homogeneous organocatalytic conditions, as demonstrated by 17 examples conducted on 1 g scale. In situ NMR reaction monitoring studies support a mechanism involving catalytic PIII/PV=O cycling, where tricoordinate phosphorus compound I represents the catalytic resting state. For the catalytic conversion of o-nitrobiphenyl to carbazole, the kinetic reaction order was determined for phosphetane catalyst I (first order), substrate (first order), and phenylsilane (zeroth order). For differentially 5-substituted 2-nitrobiphenyls, the transformation is accelerated by electron-withdrawing substituents (Hammett factor ρ = +1.5), consistent with the accrual of neg. charge on the nitro substrate in the rate-determining step. DFT modeling of the turnover-limiting deoxygenation event implicates a rate-determining (3 + 1) cheletropic addition between the phosphetane catalyst and 2-nitrobiphenyl substrate to form an unobserved pentacoordinate spiro-bicyclic dioxazaphosphetane, which decomposes via (2 + 2) cycloreversion giving 1 equiv of phosphetane P-oxide and 2-nitrosobiphenyl. Exptl. and computational investigations into the C-N bond forming event suggest the involvement of an oxazaphosphirane (2 + 1) adduct between I and 2-nitrosobiphenyl, which evolves through loss of phosphetane P-oxide to give the observed carbazole product via C-H insertion in a nitrene-like fashion.

Although many compounds look similar to this compound(707-61-9)Related Products of 707-61-9, numerous studies have shown that this compound(SMILES:CC1=CP(CC1)(C2=CC=CC=C2)=O), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Name: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, is researched, Molecular C11H13OP, CAS is 707-61-9, about Synthesis of novel deoxy λ5 phospha sugar nucleosides: 1,3-dipolar cycloaddition of an azidophospholane with alkynes.

Several novel phospha sugar nucleosides, analogs of normal sugar nucleosides, were synthesized from a phospholene 1-oxide derivative Bromination of a phospholene precursor in aqueous organic medium gave regio diastereomers, the threo and erythro bromohydrins (1-bromo-1,3,4-trideoxy-1,4-C-[(R,S)-phenylphosphinylidene]-glycero-tetrofuranose). Further substitution of the threo isomer with sodium azide led to its corresponding azidophospholane (1-azido-1,3,4-trideoxy-2-methyl-1,4-C-[(R)-phenylphosphinylidene]-β-D-glycero-tetrofuranose) (I). 1,3-Dipolar cycloaddition of I with various electron-deficient and electron-rich alkynes afforded triazole derivatives that are nucleoside analogs. The strong electron-withdrawing phosphoryl group in the hemiacetal ring exerted no effect over reaction regioselectivity of the 1,3-dipolar cycloaddition, but steric effects of the alkynes played a vital role on the selectivity, since the regioisomer ratios and the rates and yields of cycloadducts changed as the bulkiness of the substituents on the acetylene changes. Structures of all compounds were unequivocally confirmed by 1H, 13C, and 31P NMR and mass spectral studies. Single crystal X-ray crystallog. anal. of some derivatives allowed determination of configuration of the phospha sugar nucleosides.

Although many compounds look similar to this compound(707-61-9)Name: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, numerous studies have shown that this compound(SMILES:CC1=CP(CC1)(C2=CC=CC=C2)=O), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, is researched, Molecular C11H13OP, CAS is 707-61-9, about Synthesis of 9H-Pyrrolo[1,2-a]indole and 3H-Pyrrolizine Derivatives via a Phosphine-Catalyzed Umpolung Addition/Intramolecular Wittig Reaction.Synthetic Route of C11H13OP.

The first umpolung addition/intramol. Wittig reaction, catalytic in phosphine, is described. The in situ phosphine oxide reduction was accomplished by the use of silane and a catalytic amount of bis(4-nitrophenyl)phosphate. This catalytic protocol is applicable to the synthesis of a wide range of functionalized 9H-pyrrolo[1,2-a]indoles and pyrrolizines (18 examples, 70-98% yields).

Although many compounds look similar to this compound(707-61-9)Synthetic Route of C11H13OP, numerous studies have shown that this compound(SMILES:CC1=CP(CC1)(C2=CC=CC=C2)=O), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide(SMILESS: CC1=CP(CC1)(C2=CC=CC=C2)=O,cas:707-61-9) is researched.Synthetic Route of C11H13OP. The article 《Part I: The Development of the Catalytic Wittig Reaction》 in relation to this compound, is published in Chemistry – A European Journal. Let’s take a look at the latest research on this compound (cas:707-61-9).

The authors have developed the first catalytic (in phosphane) Wittig reaction (CWR). The utilization of an organosilane was pivotal for success as it allowed for the chemoselective reduction of a phosphane oxide. Protocol optimization evaluated the phosphane oxide pre-catalyst structure, loading, organosilane, temperature, solvent, and base. These studies demonstrated that to maintain viable catalytic performance it was necessary to employ cyclic phosphane oxide pre-catalysts of type 1. Initial substrate studies utilized sodium carbonate as a base, and further experimentation identified N,N-diisopropylethylamine (DIPEA) as a soluble alternative. The use of DIPEA improved the ease of use, broadened the substrate scope and decreased the pre-catalyst loading. The optimized protocols were compatible with alkyl, aryl, and heterocyclic (furyl, indolyl, pyridyl, pyrrolyl, and thienyl) aldehydes to produce both disubstituted and trisubstituted olefins in moderate-to-high yields (60-96%) by using a pre-catalyst loading of 4-10 mol%. Kinetic E/Z selectivity was generally 66:34. Complete (E)-selectivity for disubstituted α,β-unsaturated products was achieved through a phosphane-mediated isomerization event. The CWR was applied to the synthesis of a known precursor to the anti-Alzheimer drug donepezil hydrochloride, on a multi-gram scale (12.2 g, 74% yield). In addition, the described CWR is the only transition-metal-free/heavy-metal-free catalytic olefination process, excluding proton-catalyzed elimination reactions. The synthesis of the target compounds was achieved (1R,3S)-rel-3-methyl-1-phenylphospholane 1-oxide, (1R,3R)-rel-3-methyl-1-phenylphospholane 1-oxide, 1-phenylphospholane 1-oxide as catalyst precursors. 2-Phenyl-1,3,2-dioxaphospholane 2-oxide, diethylphenylphosphine oxide, 5-phenyl-5H-benzo[b]phosphindole 5-oxide, (2R,2’R,5R,5’R)-1,1′-(1,2-ethanediyl)bis[2,5-bis(1-methylethyl)phospholane], 2-[2-[(2R,5R)-2,5-dimethyl-1-phospholanyl]phenyl]-1,3-dioxolane were also evaluated.

Although many compounds look similar to this compound(707-61-9)Recommanded Product: 707-61-9, numerous studies have shown that this compound(SMILES:CC1=CP(CC1)(C2=CC=CC=C2)=O), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Reference of 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, is researched, Molecular C11H13OP, CAS is 707-61-9, about Convenient method for the reduction of the double-bond of cyclic vinylphosphine oxides using borane. Author is Keglevich, Gy.; Fekete, M.; Chuluunbaatar, T.; Dobo, A.; Bocskei, Zs.; Toke, L..

The electron poor double-bond of cyclic vinylphosphine oxides is easily reduced by borane in a selective manner to give the corresponding saturated derivatives E.g., 3-methyl-1-phenyl-2,3,4,5-tetrahydro-1H-phosphole 1-oxide was formed in 71% yield upon reduction of the double bond of 1-Ph dihydrophosphole with 2.2 equiv of Me2S-BH3. Under forcing conditions, change of the functionality may also take place.

Although many compounds look similar to this compound(707-61-9)Reference of 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, numerous studies have shown that this compound(SMILES:CC1=CP(CC1)(C2=CC=CC=C2)=O), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Synthesis and application of aqueous polycarbodiimide crosslinking agent(II): aqueous anionic polycarbodiimide crosslinking agent, published in 2011-08-03, which mentions a compound: 707-61-9, Name is 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, Molecular C11H13OP, Recommanded Product: 707-61-9.

Aqueous anionic polycarbodiimide crosslinking agent was synthesized with isophorone diisocyanate(IPDI), sodium hydroxyethyl sulfonate(SHES) and 3-methyl-1-phenyl-2-phospholene-1-oxide(MPPO) as raw material. The influences of different synthesis conditions such as the hydrophilic end-blocking agent and temperature, as well as the dosage of end-blocking on the blocking reaction were investigated and the optimal technol. condition was obtained. The developed crosslinking agents were introduced to acrylic finishing agent. It show that tensile strength of the film increases from 2.813MPa to 6.147MPa; the swelling rate in water, 0.05mol/L NaOH, Bu acetate decreases from 52.3% to 26.4%, 202.4% to 140.4%, 843.2% to 354.8% resp.; and the rub fastness of dry and wet are improved by adding the crosslinking agent to the acrylic finishing agents.

Although many compounds look similar to this compound(707-61-9)Recommanded Product: 707-61-9, numerous studies have shown that this compound(SMILES:CC1=CP(CC1)(C2=CC=CC=C2)=O), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

HPLC of Formula: 707-61-9. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, is researched, Molecular C11H13OP, CAS is 707-61-9, about Synthesis and application characteristics of carbodiimide crosslinking agent.

Carbodiimide crosslinking agent was synthesized by 1,6-hexamethylene diisocyanate(HDI), polyethylene glycol monomethyl ether(MPEG Mn=350), N,N- dimethylethanolamine(DMEA) and 3-methyl-1-phenyl-2-phospholene-1-oxide. The influences of reaction temperature, the dosage of catalyst, nitrogen jet velocity, n(MPEG350)/n(DMEA)(mole ratio) and the pH value of water on the polymer properties were studied. This crosslinking agent was applied to acrylic acid modified collagen finishing agent. After adding crosslinking agent, the properties of film are better with the increase of flexibility resistance and tensile strength, swelling rate decreases and the brightness degree decreases a little.

Compounds in my other articles are similar to this one(4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide)HPLC of Formula: 707-61-9, you can compare them to see their pros and cons in some ways,such as convenient, effective and so on.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Related Products of 707-61-9. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, is researched, Molecular C11H13OP, CAS is 707-61-9, about Synthesis of photosensitive polycarbodiimide. Author is Mochizuki, Amane; Takeshi, Kazumasa; Haba, Osamu; Kato, Sadao; Ueda, Mitsuru.

A neg.-working photosensitive polymer based on polycarbodiimide (PCD) and {[(4,5-dimethoxy-2-nitrobenzyl)oxy]carbonyl}-2-methylpiperidine (I) as a photoamine generator(PAG) has been developed. The end-capped PCDs with number average mol. weights of 1500 and 2500 were prepared by polycondensation of tolylene 2,4-diisocyanate (TDI) in the presence of m-tolyl isocyanate and 3-methyl-1-phenyl-2-phospholene-1-oxide as an end-capping agent and a catalyst, resp. PCDs were amorphous and soluble in common organic solvents, such as toluene, chloroform, and cyclohexanone. Thermogravimetry of the polymers showed good thermal stability, indicating that a 10% weight loss of the polymers was at 480° in nitrogen. The PCD films were transparent above 360 nm. The PCD containing I showed a sensitivity of 225 mJ/cm2 and a contrast of 1.5, when it was post-baked at 90°C sec, followed by development with toluene at 25°C.

Although many compounds look similar to this compound(707-61-9)Related Products of 707-61-9, numerous studies have shown that this compound(SMILES:CC1=CP(CC1)(C2=CC=CC=C2)=O), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Quality Control of 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, is researched, Molecular C11H13OP, CAS is 707-61-9, about Preparation and characterization of novel 4-bromo-3,4-dimethyl-1-phenyl-2-phospholene 1-oxide and the analogous phosphorus heterocycles or phospha sugars. Author is Yamada, Manabu; Yamashita, Mitsuji; Suyama, Takuya; Yamashita, Junko; Asai, Kazuhide; Niimi, Taishi; Ozaki, Nobuhisa; Fujie, Michio; Maddali, Kasthuraiah; Nakamura, Satoki; Ohnishi, Kazunori.

4-Bromo-3,4-dimethyl-1-phenyl-2-phospholene 1-oxide (3c) was 1st synthesized from 3,4-dimethyl-1-phenyl-2-phospholene 1-oxide (2c) by a bromo-radical substitution reaction occurred at C-4 position by N-bromosuccinimide and 2,2′-azobisisobutyronitrile. The novel phospha sugar analog 3c exerted high anti-proliferative effect on U937 cells evaluated by MTT in vitro methods and was much more efficient than that of Gleevec, which is known as a mol. targeting chemotherapeutical agent. The substitution of 2-phospholenes at C-3 and C-4 position with Me groups as well as 4-bromo substituent suggests a good anti-proliferative effect.

Although many compounds look similar to this compound(707-61-9)Quality Control of 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide, numerous studies have shown that this compound(SMILES:CC1=CP(CC1)(C2=CC=CC=C2)=O), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Tong, Rong; Pang, Xiaoyan; Sun, Jing; Ding, Zhiwen; Jia, Jizhang researched the compound: 4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide( cas:707-61-9 ).SDS of cas: 707-61-9.They published the article 《Synthesis and application of aqueous polycarbodiimide crosslinking agent(I): aqueous cationic polycarbodiimide crosslinking agent》 about this compound( cas:707-61-9 ) in Zhongguo Pige. Keywords: aqueous cationic polycarbodiimide crosslinking agent synthesis. We’ll tell you more about this compound (cas:707-61-9).

Aqueous cationic polycarbodiimide crosslinking agent was synthesized with isophorone diisocyanate (IPDI), polypropylene glycol (PPG400), N,N-dimethylethanolamine (DMEA) and 3-methyl-1-phenyl-2-phosopholene-1-oxide (MPPO) as raw materials. The influences of synthesis conditions such as the dosage of catalyst, reaction time, reaction temperature, nitrogen jet velocity, hydrophilic end-blocking agent, end-blocking temperature and the dosage of end-blocking agent on the blocking reaction were investigated. The developed crosslinking agents were applied to protein finishing agent. And it is found that the properties of obtained finishing film agent are better in the water resistance, alkali resistance, solvent resistance and flexibility. Also, the tensile strength of film increases with a little decrease in brightness and transparency.

Although many compounds look similar to this compound(707-61-9)SDS of cas: 707-61-9, numerous studies have shown that this compound(SMILES:CC1=CP(CC1)(C2=CC=CC=C2)=O), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem