Category: 6413-10-1

Catalytic synthesis of ketal over lanthanium trichloride was written by He, Jieyu;Chen, Xiantao. And the article was included in Jingxi Shiyou Huagong in 2006.Computed Properties of C8H14O4 The following contents are mentioned in the article:

With solid LaCl₃ as catalyst to replace conventional liquid inorganic acid, and ketalization between cyclohexanone and 1,2-propanediol as a probe reaction, the optimal conditions of ketalization were investigated and various ketals were synthesized. The catalyst had good catalytic activity in ketalization. The drawbacks brought by using conventional liquid inorganic acid to catalyze ketalization could be avoided. Under the optimal conditions, i.e., 0.1 mol cyclohexanone, 0.12 mol 1,2-propanediol, 1.0 g catalyst, reaction time 90 min, reaction temperature 150°C and 10 mL toluene as water entrainer, the yield of cyclohexanone 1,2-propanediol ketal was above 90%. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Computed Properties of C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Acetalization of ethyl acetoacetate with ethylene glycol using heteropolyacid H₃PW₁₂O₄₀ supported on active carbon as catalyst was written by Yu, Qingyue;Wu, Wenliang;Xu, Ning. And the article was included in Yingyong Huagong in 2006.SDS of cas: 6413-10-1 The following contents are mentioned in the article:

Catalysts were prepared by impregnation method of phosphor-tungstic acid supported on activated carbon dealt with surfactant and characterized by temperature-programmed adsorption of probe mol. ammonia (NH₃-TPD) techniques. While PW loading was as high as 30%, the acid amount was the largest. Thirty percent PW/C exhibited higher catalytic activity than other PW/C catalysts, the yield of fructone was 87.5%. The suitable reaction temperature was 80°. and the optimal reaction time was 30 min while the ratio of Et acetoacetate to glycol was 1:1.5, the catalyst treated with surfactant could be used 9 cycles, the yield of fructone was over 85%. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1SDS of cas: 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.SDS of cas: 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Synthesis of fructone over heteropolyacid supported on activated carbon was written by Yu, Qing-yue;Yang, Yu-ying. And the article was included in Jiangsu Huagong in 2007.Safety of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate The following contents are mentioned in the article:

Fructone (2 – Me – 2 – Et – acetoacetate – 1,3 – dioxolane) was obtained by acetalization of Et acetoacetate with ethylene glycol using phosphotungstic acid (PW) supported on activated carbon (AC) treated with surfactant as the catalyst. With the loading amount achieved 30%, PW could be well dispersed on the activated carbon because of the host – guest interaction. 30% PW/AC exhibited the highest activity among the PW/AC catalysts due to its largest acidity. The optimal reaction conditions were determined as 80 °C and 0.5 h while the ration of Et acetoacetate to glycol was fixed to 1 : 1.5, in which the catalysts could be recycle used for 9 times. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Safety of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Safety of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Synthesis of acetals and ketals sodium hydrogen sulfate-doped polyaniline as catalyst was written by He, Miao;Zhou, Haixia;Zhang, Shaohua;Liu, Chunsheng;Luo, Genxiang. And the article was included in Xiangliao Xiangjing Huazhuangpin in 2006.Electric Literature of C8H14O4 The following contents are mentioned in the article:

A new environmentally friendly catalyst, PAn-NaHSO₄ was prepared Cyclohexanone 1,2-propylene ketal was synthesized from cyclohexanone and 1,2-propylene glycol in the presence of polyaniline doped with sodium hydrogen sulfate. Several factors influencing the product yield were discussed and the optimum reaction conditions were discovered. Polyaniline doped with sodium hydrogen sulfate was an excellent catalyst. With n(cyclohexanone) : n(1,2-propylene glycol) = 1:1.5, w(polyaniline doped with sodium hydrogen sulfate) = 1%, cyclohexane 12 mL and reaction time 1.5 h, the yield of cyclohexanone 1,2-propylene ketal reached 92%. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Electric Literature of C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Electric Literature of C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Synthesis of acetals and ketals catalyzed by dibutyltin(IV) sulfonates was written by Zhao, Li-Fang;Wang, Hong-She;Miao, Jian-Ying. And the article was included in Youji Huaxue in 2008.COA of Formula: C8H14O4 The following contents are mentioned in the article:

A method for the synthesis of the above-mentioned title catalysts [i.e., (benzenesulfonate-κO,κO‘)dibutyltin and (methanesulfonate-κO,κO‘)dibutyltin] is reported here. A reaction of dibutyltin oxide with benzenesulfonic acid or methanesulfonic acid gave two dibutyltin(IV) sulfonates which were used as the catalysts for the synthesis of acetals and ketals. The optimal reaction conditions were obtained by orthogonal experiments The advantages of the present procedure are high yields and short reaction time. Furthermore, the catalysts could be recovered easily by filtration and reused efficiently. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1COA of Formula: C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.COA of Formula: C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Highly efficient acetalization and ketalization catalyzed by cobaloxime under solvent-free condition was written by Zong, Yang;Yang, Liting;Tang, Shanyu;Li, Longjia;Wang, Wanjie;Yuan, Bingxin;Yang, Guanyu. And the article was included in Catalysts in 2018.Related Products of 6413-10-1 The following contents are mentioned in the article:

An efficient catalytic system was developed for the acetalization and ketalization of carbonyl compounds with polyhydric alcs. under mild solvent-free conditions. In the presence of 0.1 mol% CoCl₂ and 0.2 mol% dimethylglyoxime at 70° under 5 KPa pressure for 1 h, 95.3% conversion of cyclohexanone and 100% selectivity of the corresponding cyclic ketal could be obtained, where TOF reached as high as 953 h^-1. It is proposed that the in situ generated planar tetracoordinate cobaloxime played the key role in the catalytic cycle and was responsible for the excellent catalytic performance. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Related Products of 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Related Products of 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Preparation of fructone catalyzed by water-soluble Bronsted acid ionic liquids was written by Wang, Yuan Yuan;Wang, Rong;Wu, Liang Chun;Dai, Li Yi. And the article was included in Chinese Chemical Letters in 2007.COA of Formula: C8H14O4 The following contents are mentioned in the article:

Fructone (2-methyl-2-ethylacetoacetate-1,3-dioxolane), a flavoring material, was synthesized from Et acetoacetate and glycol using five water-soluble Bronsted acid ionic liquids as catalysts for the first time. The used Bronsted acid ionic liquids include [Hmim]Tfa, [Hmim]Tsa, [Hmim]BF₄, [Bmim]HSO₄, and [Bmim]H₂PO₄, and [Hmim]BF₄ showed the highest catalytic activity for the preparation of fructone. After reaction, the product could be isolated from the reaction system automatically, and the ionic liquid could be directly reused without dehydration. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1COA of Formula: C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.COA of Formula: C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Catalytic synthesis of 2-methyl-2-ethoxycarbonylmethyl-1,3-dioxolane with iodine doped polyaniline was written by Yang, Shuijin;Yin, Guojun;Lu, Baolan. And the article was included in Jingxi Shiyou Huagong Jinzhan in 2011.Safety of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate The following contents are mentioned in the article:

2-Methyl-2-ethoxycarbonylmethyl-1,3-dioxolane was synthesized by the reaction of Et acetylacetate with glycol with I₂/PAn as the catalyst, and the effect of I₂/PAn on the catalytic activity of ketal reaction as well as the effect of molar ratio of materials, catalyst usage and reaction time on product yield were studied. According to the results, I₂/PAn is a good catalyst for synthesizing 2-methyl-2-ethoxycarbonylmethyl-1,3-dioxolane. The optimum reaction conditions were identified, i.e. n(Et acetylacetate):n(glycol) = 1:1.6, percentage of catalyst amount in total mass of reaction materials: 0.6%, water carrying agent: cyclohexane, and reaction time: 45 min. The yield of 2-methyl-2-ethoxycarbonylmethyl-1,3-dioxolane can reach 86.2% at above conditions. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Safety of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Safety of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Preparation and application of magnetic solid acid SO₄^2--/ZrO₂/Fe₃O₄/WO₃ for synthesis of fructone was written by Ren, Bo;Fan, Meiqing;Wang, Jun;Jing, Xiaoyan. And the article was included in Solid State Sciences in 2011.Synthetic Route of C8H14O4 The following contents are mentioned in the article:

A synthesis route to SO₄^2--/ZrO₂/Fe₃O₄/WO₃ solid acid catalysts with magnetism is reported through chem. co-precipitation method. The obtained solid acid catalysts are characterized in detail by x-ray diffraction, Different Scanning Calorimetry (DSC), TEM, Vibrating Sample Magnetometer (VSM), N₂ adsorption-desorption, Temperature-Programmed Pesorption (TPD) of ammonia. The introduction of WO₃ and Fe₃O₄ strongly inhibit the phase transformation of zirconia and improve the thermal stability of zirconia. Furthermore, the obtained materials present super-paramagnetism and magnetism. The super acid exhibits high catalytic activity in forming fructone by condensation. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Synthetic Route of C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Synthetic Route of C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Preparation of fructone catalyzed by aluminum sulfate in ionic liquid medium was written by Lin, Qi;Li, Xinzhong;Chen, Yiting;Lou, Benyong. And the article was included in Journal of Saudi Chemical Society in 2011.Application In Synthesis of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate The following contents are mentioned in the article:

Fructone [synthetic aroma, apple ketal 2,4-dimethyl-2-ethylacetoacetate-1,3-dioxolane, 2-methyl-1,3-dioxolane-2-acetic acid Et ester] was prepared from Et acetoacetate (EAA) with 1,2-propanediol (PPO) catalyzed by aluminum sulfate in the presence of an ionic liquid A combination of aluminum sulfate and [bmim]BF₄ exhibited good catalytic activity and high selectivity towards fructone. A synergistic effect of aluminum sulfate and [bmim]BF₄ on the acetalization (ketalization) was observed After the reaction was complete, the products could be separated from the reaction mixture extraction with di-Me ether and the catalyst and ionic liquid could be directly recycled several times without a significant decrease in the activity and selectivity towards fructone. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Application In Synthesis of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Application In Synthesis of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem