Category: 177-10-6

Liu, Taotao et al. published their research in RSC Advances in 2014 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Recommanded Product: 1,4-Dioxaspiro[4.5]decane

Zeolite nanofiber assemblies as acid catalysts with high activity for the acetalization of carbonyl compounds with alcohols was written by Liu, Taotao;Fu, Wenqian;Zheng, Xiang;Jiang, Jun;Hu, Maolin;Tang, Tiandi. And the article was included in RSC Advances in 2014.Recommanded Product: 1,4-Dioxaspiro[4.5]decane This article mentions the following:

Zeolite nanofiber assemblies (HNB-MOR) as efficient heterogeneous catalysts for the formation of a range of acetals in good yields. The mesoporosity of HNB-MOR benefits mass transfer, and the strong acidic sites on HNB-MOR facilitate acetalization activity. The catalyst can be reused 10 times without loss of activity. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Recommanded Product: 1,4-Dioxaspiro[4.5]decane).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Recommanded Product: 1,4-Dioxaspiro[4.5]decane

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Liu, Zhaoyu et al. published their research in Yingyong Huaxue in 2015 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Quality Control of 1,4-Dioxaspiro[4.5]decane

Synthesis and catalytic activity of a Strandberg-type molybdophosphate modified by organic cations was written by Liu, Zhaoyu;Zhu, Haotian;Lu, Mingda;Li, Xiaohui;An, Yue;Zhang, Lancui. And the article was included in Yingyong Huaxue in 2015.Quality Control of 1,4-Dioxaspiro[4.5]decane This article mentions the following:

A Strandberg-type molybdophosphate {H4(H2biim)5(C(NH2)3)4} [H2P2Mo5O23]2 · 8H2O (1, H2biim = 2,2′-biimidazole) modified by 2,2′-biimidazole and guanidinium cations was self-assembled in aqueous solution of pH = 3-4 containing sodium molybdate, 2,2′-biimidazole, guanidine hydrochloride and an excess of phosphoric acid, and was characterized by single crystal X-ray diffraction anal., IR spectroscopy (FT-IR), themogravimetry-DTA (TG-DTA) and X-ray powder diffraction (XRD). Compound 1 has a stable 3D organic-inorganic hybrid framework. It was used as a catalyst for carbonyl-protection. The synthesis of cyclohexanone ethylene ketal was performed as an example to investigate some influence factors on the yield, such as catalyst loading, molar ratio of reactants and reaction time. The optimal conditions are: the molar ratio of catalyst (based on Mo) to ketone is 1:300, the molar ratio of ketone to alc. is 1:1.4, and reaction time is 2.5 h. The catalytic activity of compound 1 for the synthesis of four other ketals was evaluated. The results show that compound 1 is a better catalyst for the synthesis of cyclohexanone ethylene ketal. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Quality Control of 1,4-Dioxaspiro[4.5]decane).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Quality Control of 1,4-Dioxaspiro[4.5]decane

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Chen, Zhi-sheng et al. published their research in Guangzhou Huagong in 2011 | CAS: 177-10-6

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C8H14O2

The synthesis of cyclohexanone ethylene ketal catalyzed by solid superacid S2O82-/SnO2-SiO2 catalyst was written by Chen, Zhi-sheng;Guo, Hai-fu;Yan, Peng;Wang, Zhao-zhi. And the article was included in Guangzhou Huagong in 2011.Computed Properties of C8H14O2 This article mentions the following:

Cyclohexanone ethylene ketal was synthesized from cyclohexanone and ethylene glycol in the presence of solid S2O82-/SnO2-SiO2. The effect of molar ratio of cyclohexanone to ethylene glycol, catalyst amount, reaction time, and amount of the water-entraining agent on the ketalization reaction were investigated. The optimum conditions were that molar ratio of cyclohexanone to ethylene glycol was 1:1.5, cyclohexane as water-entraining agent, the quantity of catalyst was equal to 0.5% of feed stocks, and the reaction time was 1.5 h. S2O82-/SnO2-SiO2 was a good catalyst for synthesizing cyclohexanone ethylene ketal and its yield can reach 86.9%. In the experiment, the researchers used many compounds, for example, 1,4-Dioxaspiro[4.5]decane (cas: 177-10-6Computed Properties of C8H14O2).

1,4-Dioxaspiro[4.5]decane (cas: 177-10-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C8H14O2

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Yu, Hai-Feng’s team published research in Synthetic Communications in 43 | CAS: 177-10-6

Synthetic Communications published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C9H6FNO2, Category: dioxole.

Yu, Hai-Feng published the artcileChemoselective and odorless transthioacetalization of acetals using -oxo-ketene dithioacetals as thiol equivalents, Category: dioxole, the publication is Synthetic Communications (2013), 43(9), 1280-1286, database is CAplus.

Using α-oxo-ketene dithioacetals as odorless thiol equivlents, an efficient and odorless transthioacetalization of acetals has been developed. In the presence of MeCOCl in MeOH, the cleavage of commences to generate thiols at both room and reflux temperatures, and the generated thiols then react with acetals to give correspecting thioacetals e. g., I in good yield. This transthioacetalization is characterized by mild reaction conditions, simple procedure, good yields, and perfect chemoselectivity.

Synthetic Communications published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C9H6FNO2, Category: dioxole.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Liang, Xuezheng’s team published research in Kinetics and Catalysis in 54 | CAS: 177-10-6

Kinetics and Catalysis published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Application of 1,4-Dioxaspiro[4.5]decane.

Liang, Xuezheng published the artcileSynthesis of novel solid acidic ionic liquid polymer and its catalytic activities, Application of 1,4-Dioxaspiro[4.5]decane, the publication is Kinetics and Catalysis (2013), 54(6), 724-729, database is CAplus.

The novel solid acidic ionic liquid polymer was synthesized through the copolymerization of acidic ionic liquid oligomers and resorcinol-formaldehyde (RF resin). The catalytic activities were studied through the acetalization. The PIL was efficient for the reactions with the average yield over 99.0%. The procedure was quite simple with just one-step to complete both the reactions. The high hydrophobic BET surface, high catalytic activities and high stability gave the PIL great potential for green chem. processes.

Kinetics and Catalysis published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Application of 1,4-Dioxaspiro[4.5]decane.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Jia, Wei’s team published research in Guangdong Huagong in 39 | CAS: 177-10-6

Guangdong Huagong published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Application of 1,4-Dioxaspiro[4.5]decane.

Jia, Wei published the artcileMethod for synthesis of cyclohexanone-ethylene glycol ketal, Application of 1,4-Dioxaspiro[4.5]decane, the publication is Guangdong Huagong (2012), 39(2), 78, 3, database is CAplus.

The paper introduced the use of anhydrous AlCl3 as catalyst in cyclohexane, with water under the action of with cyclohexanone and ethylene glycol to get cyclohexanone-ethylene glycol ketal, and the specific technol. conditions were discussed.

Guangdong Huagong published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Application of 1,4-Dioxaspiro[4.5]decane.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Wang, Wei’s team published research in Journal of Materials Chemistry in 22 | CAS: 177-10-6

Journal of Materials Chemistry published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C3H5F3O, Recommanded Product: 1,4-Dioxaspiro[4.5]decane.

Wang, Wei published the artcileSelf-assembly synthesis of a high-content sulfonic acid group functionalized ordered mesoporous polymer-based solid as a stable and highly active acid catalyst, Recommanded Product: 1,4-Dioxaspiro[4.5]decane, the publication is Journal of Materials Chemistry (2012), 22(31), 15874-15886, database is CAplus.

A stable and highly active ordered mesoporous polymer-based acid catalyst has been prepared via a ethylene oxide-propylene oxide triblock copolymer surfactant templating of a formaldehyde-3-mercaptopropyltrimethoxysilane-phenol-tetraethoxysilane copolymer and oxidation of the HS to SO3H. The composition and nanostructure are characterized by XRD, NMR, XPS, TEM, nitrogen sorption, elemental and chem. anal. The sulfonic acid groups have been anchored within the well-arranged channels of the polymer-based matrix. Even with a high SO3H group loading (up to about 27.4 wt%) on the mesoporous polymer-based material, the ordered mesostructure and high surface area (∼400 m2 g-1) can be retained and the functional moieties are highly chem. accessible. With the large number of acid sites (0.93-2.38 H+ mmol g-1 determined by acid-base titration) and the hydrophobic character, the mesoporous polymer-based solid exhibits catalytic performance in acid-catalyzed reactions such as condensation and acetalization, not only high activity (per site yield of bisphenol A is over 45 in the condensation of phenol and acetone) but also excellent stability. Loss in acidic loading and activity is negligible even after the catalyst is reused 20 times in the acetalization of butanediol and aldehyde. The stability is most likely attributed to the hydrophobic nature of the mesoporous polymer-based solids, which favors the diffusion of water and thereby inhibits the poisoning of acidic sites caused by water generating in the reaction. Moreover, with large mesopores, the diffusion of reactants and products can be promoted and hence the catalytic activity can be further increased.

Journal of Materials Chemistry published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C3H5F3O, Recommanded Product: 1,4-Dioxaspiro[4.5]decane.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Yu, Mo-han’s team published research in Wuji Huaxue Xuebao in 30 | CAS: 177-10-6

Wuji Huaxue Xuebao published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C18H28N2O7, Computed Properties of 177-10-6.

Yu, Mo-han published the artcileSynthesis, crystal structure and catalytic property of a preyssler-type polyoxometalate modified by Mn(II) complexes, Computed Properties of 177-10-6, the publication is Wuji Huaxue Xuebao (2014), 30(6), 1221-1228, database is CAplus.

A new Preyssler-type polyoxometalate modified by Mn(II)-H2biim/H2O fragments, namely {[Mn(H2biim)2(H2O)2]2[Mn(H2biim)3]5Cl}[H(NaP5W30O110)]·20H2O (1) (H2biim = 2,2′-biimidazole) has been hydrothermally synthesized, and characterized by single-crystal x-ray diffraction, elemental anal., TGA and electrochem. anal. Its catalytic activity for synthesis of cyclohexanone ethylene ketal has been investigated. Compound 1 contains a [NaP5W30O110]14- polyoxo anion, and seven isolated Mn(II)-H2biim/H2O complex units. A 3D framework is constructed through N-HO/OW and N-HCl hydrogen bonds between H2biim mols. and polyoxo-anion or water mols., and Cl–, and π-π interactions between the imidazole rings of biimidazole ligands. Compound 1 is a new environmentally friendly catalyst and has good recyclability for the protection of carbonyl compound

Wuji Huaxue Xuebao published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C18H28N2O7, Computed Properties of 177-10-6.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Hu, Ying-xi’s team published research in Huaxue Yu Shengwu Gongcheng in 32 | CAS: 177-10-6

Huaxue Yu Shengwu Gongcheng published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Name: 1,4-Dioxaspiro[4.5]decane.

Hu, Ying-xi published the artcileSynthesis of cyclohexanone ethylene ketal and benzaldehyde ethylene acetal by chloroaluminate ionic liquid, Name: 1,4-Dioxaspiro[4.5]decane, the publication is Huaxue Yu Shengwu Gongcheng (2015), 32(10), 42-44, database is CAplus.

Cyclohexanone ethylene ketal and benzaldehyde ethylene acetal were synthesized with chloroaluminate ionic liquid as catalyst. The effects of catalyst amount, molar ratio of cyclohexanone (benzaldehyde) to ethylene glycol, and water-carrying agent amount on the reaction were investigated. The optimum synthetic conditions were obtained as follows:catalyst amount was 1.0 g, the molar ratio of cyclohexanone (benzaldehyde) to ethylene glycol was 1:1.8, water-carrying agent amount was 30 mL. The phys. property and structure of the synthetic product were characterized by elemental anal., FTIR, refractive index and 1 H-NMR.

Huaxue Yu Shengwu Gongcheng published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Name: 1,4-Dioxaspiro[4.5]decane.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Kandasamy, Sabariswaran’s team published research in Biomass and Bioenergy in 131 | CAS: 177-10-6

Biomass and Bioenergy published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Related Products of dioxole.

Kandasamy, Sabariswaran published the artcileHydrothermal liquefaction of microalgae using Fe3O4 nanostructures as efficient catalyst for the production of bio-oil: Optimization of reaction parameters by response surface methodology, Related Products of dioxole, the publication is Biomass and Bioenergy (2019), 105417, database is CAplus.

The aim of the present work was focused on optimizing the hydrothermal liquefaction (HTL) of Spirulina platensis catalyzed by Fe3O4 nanostructures to enhance the bio-oil yield and quality of bio-oil using response surface methodol. (RSM). The structural morphol. and crystalline nature of the synthesized catalyst was determined using a scanning electron microscope (SEM), high resolution transmission electron microscopy (HR-TEM) and X-ray powder diffraction (XRD). Three of the vital reaction parameters such as temperature, holding time and catalyst dosage were optimized through central composite design. A maximum bio-oil yield of 32.33% was observed for the high temperature at 320°C, 0.75 g of catalyst dosage and 37 min of resident time. The maximum conversion was found at a lower temperature of 272°C, the bio-oil yield of 27.66% was obtained with 0.45 g of catalyst dosage and 24 min of holding time which is an energy efficient optimum condition. The maximum bio-oil yield was influenced at a lower temperature due to the high catalytic activity. While compared to higher temperatures were not much influence was observed It clearly states that the catalyst dosage playing a critical role in the lower temperature HTL reaction. GC-MS and FT-IR anal. of the produced bio-oil exhibits significant characteristics for biofuel applications. The Fe3O4 catalyst was recyclable for up to eight repeated cycles and constant bio-oil yield for the last four cycles. It shows the excellent reproduction ability towards HTL of Spirulina sp.

Biomass and Bioenergy published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Related Products of dioxole.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem