Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 1265884-98-7, is researched, SMILESS is N1(P2OC3=CC=C4C=CC=CC4=C3C5=C6C=CC=CC6=CC=C5O2)C7=CC=CC=C7C=CC8=CC=CC=C81, Molecular C34H22NO2PJournal, Article, Angewandte Chemie, International Edition called Iridium-Catalyzed Enantioselective Allylic Alkylation with Functionalized Organozinc Bromides, Author is Hamilton, James Y.; Sarlah, David; Carreira, Erick M., the main research direction is carbonate racemic enantioselective regioselective allylic alkylation organozinc iridium catalyst; alkene branched asym synthesis; alkylation; allylic compounds; enantioselectivity; iridium; zinc.Electric Literature of C34H22NO2P.
Iridium-catalyzed enantioselective allylic alkylation of branched racemic carbonates R1CH(OBoc)CH:CH2 (R1 = MeCH:CH, Ph, 3-MeOC6H4, 3-thienyl, 2-naphthyl, PhCH2CH2CC, etc.) with functionalized alkylzinc bromide reagents R2ZnBr [R2 = EtO2C(CH2)3, NC(CH2)4, 1,3-dioxolan-2-ylmethyl, etc.] is described. Enabled by a chiral Ir/(P,olefin) complex, this method allows allylic substitution with various primary and secondary alkyl nucleophiles with excellent regio- and enantioselectivities. The developed reaction was showcased in a concise, asym. synthesis of (-)-preclamol.
After consulting a lot of data, we found that this compound(1265884-98-7)Electric Literature of C34H22NO2P can be used in many types of reactions. And in most cases, this compound has more advantages.
Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem