Redox-Neutral Ni-Catalyzed sp3 C-H Alkylation of α-Olefins with Unactivated Alkyl Bromides was written by Buendia, Mikkel B.;Higginson, Bradley;Kegnaes, Soeren;Kramer, Soeren;Martin, Ruben. And the article was included in ACS Catalysis in 2022.Synthetic Route of C6H11BrO2 This article mentions the following:
A light-induced redox-neutral Ni-catalyzed sp3 C-H alkylation of unactivated alkenes with alkyl bromides possessing β-hydrogens is described herein. The method is distinguished by its simplicity, wide scope, and exquisite regio- and chemoselectivity profile, thus offering an entry point to forge sp3-sp3 architectures. In the experiment, the researchers used many compounds, for example, 2-(3-Bromopropyl)-1,3-dioxolane (cas: 62563-07-9Synthetic Route of C6H11BrO2).
2-(3-Bromopropyl)-1,3-dioxolane (cas: 62563-07-9) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Synthetic Route of C6H11BrO2
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem