Total Synthesis of (-)-Anominine was written by Bradshaw, Ben;Etxebarria-Jardi, Gorka;Bonjoch, Josep. And the article was included in Journal of the American Chemical Society in 2010.Name: 2-Ethyl-2-methyl-1,3-dioxolane This article mentions the following:
The first total synthesis of anominine [(-)-I] has been achieved, and the absolute configuration of the product has been determined The key features include the development of a new, highly efficient organocatalyzed method for the asym. synthesis of Wieland-Miescher ketone building blocks, an unusual selenoxide [2,3]-sigmatropic rearrangement, and a ZrCl4-catalyzed indole coupling as well as several chemoselective transformations controlled by the structurally congested nature of the bicyclic core. In the experiment, the researchers used many compounds, for example, 2-Ethyl-2-methyl-1,3-dioxolane (cas: 126-39-6Name: 2-Ethyl-2-methyl-1,3-dioxolane).
2-Ethyl-2-methyl-1,3-dioxolane (cas: 126-39-6) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Name: 2-Ethyl-2-methyl-1,3-dioxolane
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem