Synthesis of 1,3-dioxolanes from natural carbonyl compounds was written by Beresnevich, L. B.;Moiseichuk, K. L.. And the article was included in Vestsi Natsyyanal’nai Akademii Navuk Belarusi, Seryya Khimichnykh Navuk in 2009.Product Details of 68527-74-2 This article mentions the following:
Condensation of various naturally occurring aldehydes and ketones R1R2CO [R1 = H, R2 = n-Pr, i-Bu, 4-MeC6H4CH2CHMe, 4-HO-3-MeOC6H3, etc.; R1R2 = (CH2)4, (CH2)5, etc.; R1 = R2 = n-Pr; R1 = Me, R2 = Et, t-Bu, n-hexyl] with 1,2-propanediol in the presence of sulfonated cationite FIBAN K-1 neat or in benzene gave the corresponding 1,3-dioxolanes in 50-98% yields. In the experiment, the researchers used many compounds, for example, 2-Methoxy-4-(4-methyl-1,3-dioxolan-2-yl)phenol (cas: 68527-74-2Product Details of 68527-74-2).
2-Methoxy-4-(4-methyl-1,3-dioxolan-2-yl)phenol (cas: 68527-74-2) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Product Details of 68527-74-2
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem