Barker, S. A.’s team published research in Journal of the Chemical Society in | CAS: 1193-11-9

Journal of the Chemical Society published new progress about 1193-11-9. 1193-11-9 belongs to dioxole, auxiliary class Dioxolanes, name is 2,2,4-Trimethyl-1,3-dioxolane, and the molecular formula is C6H12O2, Safety of 2,2,4-Trimethyl-1,3-dioxolane.

Barker, S. A. published the artcileSpectra of acetals. II. Infrared and Raman spectra of substituted 1,3-dioxolanes, Safety of 2,2,4-Trimethyl-1,3-dioxolane, the publication is Journal of the Chemical Society (1959), 807-13, database is CAplus.

Infrared and Raman spectra have been reported for 9 substituted 1,3-dioxolanes: 2-methyl; 4-methyl; 2,2-dimethyl; cis-2,4-dimethyl; trans-2,4-dimethyl; 2,2,4-trimethyl; 4-hydroxymethyl-2,2-dimethyl; 4-deuterioöxymethyl-2,2-dimethyl; and 4-methoxymethyl-2,2-dimethyl. Infrared and Raman spectra of these compounds were measured. Some 100 bands observed are listed in a table with their assignments made by analogy with the assignments for dioxolane. Internal vibrations of the methyl groups were made by use of the review of Sheppard and Simpson (C.A. 47, 6767d). These assignments are discussed under the following headings: vibrations involving methylene groups; vibrations involving methyl substituents, including bending, rocking, stretching, and deformations of the methyl groups; C-H deformations; vibrations involving a hydroxymethyl substituent; and ring vibrations. The infrared spectra of the 3,4-O-isopropylidene ketals of L-iditol, D-mannitol, and D-sorbitol were measured over the range 650-1500 cm.-1 Assignments, made by analogy with those for the substituted dioxolanes, are given.

Journal of the Chemical Society published new progress about 1193-11-9. 1193-11-9 belongs to dioxole, auxiliary class Dioxolanes, name is 2,2,4-Trimethyl-1,3-dioxolane, and the molecular formula is C6H12O2, Safety of 2,2,4-Trimethyl-1,3-dioxolane.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem