m-Terphenyl ethers, a new hydroxy protecting group cleavable under reductive single electron transfer reaction conditions was written by Azzena, Ugo;Mocci, Sarah;Pisano, Luisa. And the article was included in Synthesis in 2011.Synthetic Route of C7H13ClO2 This article mentions the following:
2,6-Diphenylphenyl ethers and, to a lesser extent, 2,6-dimethoxyphenyl ethers, were tested as protected hydroxyl derivatives under a variety of reaction conditions. These ethers underwent regioselective cleavage of the aromatic C(1)-O bond under reductive SET reaction conditions using alkali metals in THF at room temperature This deprotective procedure was efficiently realized in the presence of several other functional groups, including an acetal, a Ph alkyl ether, an unprotected alc., and C-C double and triple bonds. Furthermore, meta-terphenyl ethers proved stable under different reaction conditions, including acidic hydrolysis and formation and/or employment of different organometallic reagents. In the experiment, the researchers used many compounds, for example, 2-(4-Chlorobutyl)-1,3-dioxolane (cas: 118336-86-0Synthetic Route of C7H13ClO2).
2-(4-Chlorobutyl)-1,3-dioxolane (cas: 118336-86-0) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Synthetic Route of C7H13ClO2
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem