Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 1265884-98-7, is researched, Molecular C34H22NO2P, about Total Synthesis of (+)-Asperolide C by Iridium-Catalyzed Enantioselective Polyene Cyclization, the main research direction is asperolide C total synthesis enantioselective polyene cyclization iridium catalyst; biomimetic synthesis; cyclization; diterpenes; iridium; total synthesis.Application of 1265884-98-7.
The first total synthesis of tetranorlabdane diterpenoid asperolide C (I) is reported. This study demonstrates the use of an enantioselective polyene cyclization for natural product synthesis and relies on modern iridium catalysis to prepare the carbobicyclic core scaffold. The synthesis also features cross-coupling reactions, specifically, the Pd-mediated coupling of a dienol triflate, H2C:CHC(OTf):CHCH2CH2OCH2C6H4OMe-4, with Me3SiCH2B(OH)2, which produces an allylic silane.
Here is just a brief introduction to this compound(1265884-98-7)Application of 1265884-98-7, more information about the compound(5-(11bR)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine) is in the article, you can click the link below.
Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem