Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 707-61-9, is researched, SMILESS is CC1=CP(CC1)(C2=CC=CC=C2)=O, Molecular C11H13OPJournal, Article, Research Support, N.I.H., Extramural, Research Support, Non-U.S. Gov’t, Journal of the American Chemical Society called Intermolecular Reductive C-N Cross Coupling of Nitroarenes and Boronic Acids by PIII/PV=O Catalysis, Author is Nykaza, Trevor V.; Cooper, Julian C.; Li, Gen; Mahieu, Nolwenn; Ramirez, Antonio; Luzung, Michael R.; Radosevich, Alexander T., the main research direction is nitroarene boronic acid reductive intermol cross coupling hexamethylphosphetane catalyst; arylamine preparation chemoselectivity.COA of Formula: C11H13OP.
A main group-catalyzed method for the synthesis of aryl- and heteroarylamines by intermol. C-N coupling is reported. The method employs a small-ring organophosphorus-based catalyst (1,2,2,3,4,4-hexamethylphosphetane) and a terminal hydrosilane reductant (phenylsilane) to drive reductive intermol. coupling of nitro(hetero)arenes with boronic acids. Applications to the construction of both Csp2-N (from arylboronic acids) and Csp3-N bonds (from alkylboronic acids) are demonstrated; the reaction is stereospecific with respect to Csp3-N bond formation. The method constitutes a new route from readily available building blocks to valuable nitrogen-containing products with complementarity in both scope and chemoselectivity to existing catalytic C-N coupling methods.
In some applications, this compound(707-61-9)COA of Formula: C11H13OP is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem