Name: 5-(11bR)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 5-(11bR)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine, is researched, Molecular C34H22NO2P, CAS is 1265884-98-7, about Iridium-catalyzed enantioselective allyl-allylsilane cross-coupling. Author is Hamilton, James Y.; Hauser, Nicole; Sarlah, David; Carreira, Erick M..
An enantioselective allyl-allylsilane cross-coupling involving racemic branched allylic alcs. and allylsilanes was reported. An iridium-(P,olefin) phosphoramidite complex enabled the transformation with high regio- and stereoselectivity under operationally simple conditions. The utility of the coupling was demonstrated in a concise catalytic, enantioselective synthesis of a pyrethroid insecticide protrifenbute. The structure of the compound (3R,4S)-3-methyl-4-(naphthalen-2-yl)hexane-1,6-diol was confirmed by the single crystal x-ray diffraction anal. and its data were deposited at the Cambridge Crystallog. Data Center as supplementary publication number CCDC 1005708.
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Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem