Preparation of the WOX/MCM-41 Solid Acid Catalyst and the Catalytic Performance for Solketal Synthesis was written by Huang, Yixuan;Zhang, Guangcai;Zhang, Qinhui. And the article was included in ACS Omega in 2021.Electric Literature of C6H12O3 This article mentions the following:
In the present work, an efficient and stable WOX/MCM-41 solid acid catalyst was prepared by the wet impregnation method. The characterization of powder X-ray diffraction, transmission electron microscopy, UV-visible, H2 temperature-programmed reduction, XPS, NH3 temperature-programmed desorption, and N2 adsorption-desorption isotherms confirmed that the impregnation amount and calcination temperature of WOX speciation affected the dispersity and acidity of the resulting catalyst. This WOX/MCM-41 solid acid catalyst was subsequently applied in the ketalization reaction of glycerol and acetone to produce solketal. By catalyst screening and reaction condition optimization, WOX/MCM-41 obtained by impregnating 20 weight % and calcining at 350°C exhibited the highest solketal yield and catalytic stability. In the experiment, the researchers used many compounds, for example, (2,2-Dimethyl-1,3-dioxolan-4-yl)methanol (cas: 100-79-8Electric Literature of C6H12O3).
(2,2-Dimethyl-1,3-dioxolan-4-yl)methanol (cas: 100-79-8) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Electric Literature of C6H12O3
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem