Ruthenium(II)biscarboxylate-Catalyzed Hydrogen-Isotope Exchange by Alkene C-H Activation was written by Bechtoldt, Alexander;Ackermann, Lutz. And the article was included in ChemCatChem in 2019.Name: 2-Bromomethyl-1,3-dioxolane This article mentions the following:
Ruthenium(II) biscarboxylate catalysis enabled efficient hydrogen isotope exchange of acrylic C-H bonds with user-friendly D2O. The C-H labeling was characterized by excellent positional selectivity and a broad functional group tolerance. The deuteration was successfully conducted on 55 mmol scale with TONs of >1000, while mechanistic studies provided insights into ruthenium(II) oxidase catalysis. The obtained deuterated alkenes enabled the synthesis of labeled standards for mass spectrometry of irradiated foodstuffs. In the experiment, the researchers used many compounds, for example, 2-Bromomethyl-1,3-dioxolane (cas: 4360-63-8Name: 2-Bromomethyl-1,3-dioxolane).
2-Bromomethyl-1,3-dioxolane (cas: 4360-63-8) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Name: 2-Bromomethyl-1,3-dioxolane
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem