Electrochemical oxidation of conjugated arylolefins to α-bromoketals was written by Nikishin, Gennady I.;Elinson, Michail N.;Makhova, Irina V.. And the article was included in Tetrahedron Letters in 1988.Recommanded Product: 2-(Bromomethyl)-2-phenyl-1,3-dioxolane This article mentions the following:
Conjugated arylolefins electrolyzed in alcs. in the presence of alkali metal bromides were transformed into α-bromoketals. Thus RC6H4CH:CHR1 (R = R1 = H; R = p-Me, R = H; R = m-Cl, R1 = H; R = H, R1 = Me; R = p-MeO, R1 = Me) was electrolyzed in MeOH containing NaBr in an undivided cell with a Pt anode, Cu-Zn (60:40) cathode at 60° under constant c.d. 220 mA/cm2. RC6H4C(OMe)2CHR1Br was formed. Electrolysis of C6H5CH:CH2 in ethylene glycol gave cyclic α-bromoketal. In the experiment, the researchers used many compounds, for example, 2-(Bromomethyl)-2-phenyl-1,3-dioxolane (cas: 3418-21-1Recommanded Product: 2-(Bromomethyl)-2-phenyl-1,3-dioxolane).
2-(Bromomethyl)-2-phenyl-1,3-dioxolane (cas: 3418-21-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Recommanded Product: 2-(Bromomethyl)-2-phenyl-1,3-dioxolane
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem