Acetalization of carbonyl compounds catalyzed by iodine-doped polyaniline was written by Luo, Genxiang;He, Miao;Zhong, Zhaojin. And the article was included in Polymer-Plastics Technology and Engineering in 2008.Application In Synthesis of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate The following contents are mentioned in the article:
Polyaniline-I2 is prepared by doping of polyaniline base with iodine. Polyaniline base and polyaniline-I2 are characterized by IR spectra, X-ray diffraction spectra, and thermogravimetric anal. Polyaniline-I2 is used as a catalyst for the first time in acetalization of carbonyl compounds The catalyzing acetalization of cyclohexanone and propane-1,2-diol is conducted in excellent yields with simple and more environmental benign procedure. This catalyst could also catalyze acetalization of aromatic and aliphatic carbonyl compounds with satisfactory yields. The use of polyaniline-I2 catalyst is feasible because of its easy preparation, easy handling, stability, easy recovery, reusability, good activity, and eco-friendly nature. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Application In Synthesis of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate).
Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Application In Synthesis of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem