Zhu, Haotian’s team published research in Yingyong Huaxue in 32 | CAS: 177-10-6

Yingyong Huaxue published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C17H14O5, COA of Formula: C8H14O2.

Zhu, Haotian published the artcileSynthesis, crystal structure and catalytic activity of a Dawson-type tungstophosphate decorated by copper complexes, COA of Formula: C8H14O2, the publication is Yingyong Huaxue (2015), 32(4), 433-441, database is CAplus.

An inorganic-organic hybrid compound [Cu(H2biim)2(H2O)][{Cu(H2biim)2}2(P2W18O62)]·11H2O (H2biim = 2,2′-biimidazole) (1) was hydrothermally constructed by the reaction of Cu(II)-H2biim complexes and Dawson-type tungstophosphate, and characterized by single-crystal x-ray diffraction, IR spectroscopy (IR), X-ray powder diffraction (XRD), elemental anal. and electrochem. anal. Structural anal. showed that the polyanion [P2W18O62]6-, as a bidentate ligand, coordinates with two Cu2+ ions to form a bi-Cu(II)-supporting heteropolyanion [{Cu(H2biim)2}2(P2W18O62)]2-, which was surrounded by an isolated [Cu(H2biim)2(H2O)]2+ and eleven H2O mols. The presence of N-H···O/OW hydrogen bonds between H2biim mols. and polyoxoanion or water mols., in company with the synergistic effect of electrostatic interactions and π-π stack, gave a crystal material with 3-dimensional framework further. Compound 1 displayed good electrocatalytic activity toward the reduction of H2O2 and Na2NO2. Meanwhile it was also a good acid-catalyst for the synthesis of cyclohexanone ethylene ketal and could be recycled.

Yingyong Huaxue published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C17H14O5, COA of Formula: C8H14O2.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem