Lu, Ting published the artcileFour Strandberg-type polyoxometalates with organophosphine centre decorated by transition metal-2,2′-bipy/H2O complexes, Recommanded Product: 1,4-Dioxaspiro[4.5]decane, the publication is Journal of Solid State Chemistry (2017), 52-57, database is CAplus.
Four inorganic-organic hybrid compounds composed of Strandberg-type organophosphomolybdate anion [(C6H5PO3)2Mo5O15]4- (abbreviated as (PhP)2Mo5) and transition metal (TM)-2,2′-bipy/H2O complex units, namely [(TM(H2O)(bipy))2(C6H5PO3)2Mo5O15]n (TM = Co, (1); Ni, (2)), [(Cu(bipy)2)2(C6H5PO3)2Mo5O15]·2H2O (3) and [(Zn(bipy)(μ-OH))2(Zn(bipy)2(C6H5PO3)2Mo5O15)2]·3H2O (4) (bipy = 2,2′-bipyridine), were successfully constructed under hydrothermal conditions, and their structures were determined by single crystal x-ray diffraction anal. and spectroscopic methods. The central heteroatoms in these polyoxometalates (POMs) are all organophosphine (RP) groups. Compound 1 and compound 2 are isostructural (PhP)2Mo5-based TM-coordination polymers with the two-dimensional layer frameworks. In compound 3, the bi-supporting structure containing one (PhP)2Mo5 unit and two [Cu(bipy)2]2+ cations. For compound 4, it can be regarded as a dimer of two bi-supporting {Zn(bipy)2(PhP)2Mo5Zn(bipy)} clusters that were connected by two μ-OH groups. The acid-catalytic activities and fluorescence properties of the four hybrids have been investigated.
Journal of Solid State Chemistry published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C8H14O2, Recommanded Product: 1,4-Dioxaspiro[4.5]decane.
Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem