On August 19, 2005, Gallos, John K.; Stathakis, Christos I.; Kotoulas, Stefanos S.; Koumbis, Alexandros E. published an article.Synthetic Route of 38838-06-1 The title of the article was An Improved Approach to Chiral Cyclopentenone Building Blocks. Total Synthesis of Pentenomycin I and Neplanocin A. And the article contained the following:
An improved approach to enantiomerically pure hydroxylated cyclopentenones is reported here, which involves intramol. nitrone cycloaddition of sugar-derived chiral pent-4-enals and hex-5-en-ones-2 followed by N-O bond cleavage, quaternization of the amine thus produced, and finally oxidative elimination of the amino group. Synthesis of pentenomycin I and neplanocin A is described following this methodol. The experimental process involved the reaction of (3aS,4S,6R,6aR)-4-(Iodomethyl)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxole(cas: 38838-06-1).Synthetic Route of 38838-06-1
The Article related to oxidative elimination synthesis pentenomycin neplanocin cycloaddition cyclopentenone pentenal, intramol nitrone cycloaddition cyclopentenone pentenal enone bond cleavage quaternization and other aspects.Synthetic Route of 38838-06-1
Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem