The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 2-Bromomethyl-1,3-dioxolane( cas:4360-63-8 ) is researched.Name: 2-Bromomethyl-1,3-dioxolane.Ramakrishna, Kolluri; Sreenivasulu, Reddymasu; Rao, Mandava Venkata Basaveswara; Vidavalur, Siddaiah; Reddy, Boggu Jagan Mohan published the article 《Stereoselective total synthesis of diplodialide A》 about this compound( cas:4360-63-8 ) in Chemical Papers. Keywords: diplodialide A stereoselective synthesis. Let’s learn more about this compound (cas:4360-63-8).
An efficient stereoselective total synthesis of diplodialide A I was achieved from inexpensive and com. available starting material (R)-propylene oxide. This linear synthesis utilizes Wittig reaction, alkylation of 1,3-dithiane and Yamaguchi macrolactonization as key steps.
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Reference:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem