Chemical Research Letters, April 2021. As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. COA of Formula: https://www.ambeed.com/products/526-95-4.html526-95-4, Name is Gluconic Acid (contains Gluconolactone), SMILES is O[C@H]([C@H]([C@@H]([C@@H](CO)O)O)O)C(O)=O, belongs to dioxole compound. In a article, author is Anac, O, introduce new discover of the category.
Carbonyl ylides arising from ethyl acetodiazoacetate/dimethyl diazomalonate and a,beta-enones with mainly s-cis conformations underwent disrotatory cyclization to produce dihydrofuran derivatives. This process proved to be sensitive to steric effects. The corresponding ylides arising from rather s-trans a,beta-enals yielded dioxole derivatives. The mechanisms of the reactions are discussed.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 526-95-4. COA of Formula: https://www.ambeed.com/products/526-95-4.html.
Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem