New discoveries in chemical research and development in 2021. As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 98760-08-8, Name is (2R,3S)-1,2-Epoxy-3-(Boc-amino)-4-phenylbutane, molecular formula is C15H21NO3. In an article, author is Thommen, Christophe,once mentioned of 98760-08-8, Recommanded Product: (2R,3S)-1,2-Epoxy-3-(Boc-amino)-4-phenylbutane.
Collective Syntheses of Icetexane Natural Products Based on Biogenetic Hypotheses
A divergent synthesis of 10 icetexane natural products based on a proposed biogenetic cationic ring expansion of a reduced carnosic acid derivative is described. Of these icetexanes, (+)-salvicanol, (-)-cyclocoulterone, (-)-coulterone, (-)-obtusinone D, and (-)-obtusinone E have been synthesized for the first time. In addition, the hypothesis for the non-enzymatic biogenesis of benzo[1,3]dioxole natural products has been experimentally investigated. Additional experimental evidence for the abiotic formation of the methylenedioxy unit is provided, as photolysis of the quinone (+)-komaroviquinone resulted in the formation of the [1,3]dioxole-containing natural product (-)-cyclocoulterone and (+)-komarovispirone.
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Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem