Chemical Research Letters, April 2021. As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. Recommanded Product: 604-69-3604-69-3, Name is beta-D-Glucose pentaacetate, SMILES is CC(O[C@H]1[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)=O, belongs to dioxole compound. In a article, author is Kiskan, Fusun Seyma, introduce new discover of the category.
Synthetic strategies towards the carbenoid reactions of alpha,beta-acetylenic carbonyls
Catalytic reactions of alpha, beta-conjugated carbonyl compounds have been a practical tool towards the synthesis of different useful heterocyclic compounds. Despite the numerous reactions with carbon-carbon double bond conjugated carbonyls, reactions of acetylenic carbonyls are limited. In this study, efficient dioxole synthesis was carried out via acetylenic aldehydes and butadiene formation was preferred over cyclopropene formation via acetylenic esters as different functional groups on these substrates change the product distribution. Both reaction conditions (such as solvent and temperature) and electrophilic structure of metal carbenoids alter the product distribution; acceptor (A), donor-acceptor (DA), and acceptor-acceptor (AA) functionalized diazo compounds yield different product types over different mechanisms.
Interested yet? Read on for other articles about 604-69-3, you can contact me at any time and look forward to more communication. Recommanded Product: 604-69-3.
Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem