The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 91526-18-0, Name is 4-(Hydroxymethyl)-5-methyl-1,3-dioxol-2-one, SMILES is CC1=C(CO)OC(=O)O1, in an article , author is Wu, Chuyi, once mentioned of 91526-18-0, HPLC of Formula: C5H6O4.
Decarboxylative Perfluoroalkylation of Vinyl Bromides with Copper(I) Perfluorocarboxylato Complexes
A new decarboxylative perfluoroalkylation of vinyl bromides has been developed. The use of copper(I) trifluoroacetate complex (phen)Cu(O2CCF3) (1) and perfluorocarboxylate complexes [(phen)(2)Cu](O2CRF) (2; R-F=C2F5, n-C3F7, n-C4F9, n-C5F11) as reagents allows for the efficient synthesis of trifluoromethylated and perfluoroalkylated olefins, respectively. Vinyl bromides comprising a range of functionalities (e.g., methoxy, ester, nitrile, nitro, trifluoromethyl, chloride, and benzo[d][1,3]dioxole) were successfully accommodated. The decarboxylative trifluoromethylation and perfluoroalkylation reactions also proceeded with retention of the double-bond stereochemistry of alkenes after the reaction was completed.
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Reference:
1,3-Benzodioxole – Wikipedia,
,Dioxole | C3H4O2 – PubChem