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Xiang, Shiyin’s team published research in Jingxi Shiyou Huagong Jinzhan in 18 | CAS: 177-10-6

Jingxi Shiyou Huagong Jinzhan published new progress about 177-10-6. 177-10-6 belongs to dioxole, auxiliary class Dioxolane,Spiro, name is 1,4-Dioxaspiro[4.5]decane, and the molecular formula is C13H18N2, Recommanded Product: 1,4-Dioxaspiro[4.5]decane.

Xiang, Shiyin published the artcileSynthesis of cyclohexanone ethylene ketal catalyzed by H₆P₂W₉Mo₉O₆₂/SiO₂, Recommanded Product: 1,4-Dioxaspiro[4.5]decane, the publication is Jingxi Shiyou Huagong Jinzhan (2017), 18(6), 45-48, database is CAplus.

H₆P₂W₉Mo₉O₆₂/SiO₂ was synthesized in a sol-gel process, and the thermal stability, structure and morphol. of H₆P₂W₉Mo₉O₆₂/SiO₂ were analyzed with X-ray diffractometer (XRD), FTIR Raman spectrometer, differential thermal analyzer (TG) and scanning electron microscope (SEM). Cyclohexanone ethylene ketal was synthesized with cyclohexanone and ethylene glycol as the reaction materials and H₆P₂W₉Mo₉O₆₂/SiO₂ as the catalyst, and the effects of the molar ratio of alc. ketone, the catalyst amount, the reaction time, and the cyclohexane amount on the synthesis of ketal were studied. According to the results, the yield of cyclohexanone ethylene ketal can reach 80.4% at the following conditions, i.e. n (cyclohexanone) : n (ethylene glycol)=1:1.3, the catalyst amount accounts for 0.8% of total reactants, and the reaction time is 45 min.

Referemce:
https://en.wikipedia.org/wiki/1,3-Benzodioxole,
Dioxole | C3H4O2 – PubChem

Krapcho, A. Paul et al. published their research in Science of Synthesis in 2006 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. 1,3-Benzodioxole can be synthesized from catechol with disubstituted halomethanes.Quality Control of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate

Product subclass 3: sodium halides and sodium cyanide was written by Krapcho, A. Paul. And the article was included in Science of Synthesis in 2006.Quality Control of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate The following contents are mentioned in the article:

A review of the applications of sodium halides and sodium cyanide in organic synthesis. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Quality Control of Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate).

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Lopez, Alberto M. et al. published their research in Organic Letters in 2018 | CAS: 6413-10-1

Correction to “Tin-Free Access to the ABC Core of the Calyciphylline A Alkaloids and Unexpected Formation of a D-Ring-Contracted Tetracyclic Core” [Erratum to document cited in CA168:398126] was written by Lopez, Alberto M.;Ibrahim, Ahmad A.;Rosenhauer, Gregory J.;Sirinimal, Hansamali S.;Stockdill, Jennifer L.. And the article was included in Organic Letters in 2018.HPLC of Formula: 6413-10-1 The following contents are mentioned in the article:

In the original publication, there are errors in scheme 6 and the first sentence of the paragraph that describes scheme 6; the correction is provided here. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1HPLC of Formula: 6413-10-1).

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Zhang, Fujuan et al. published their research in Xuchang Xueyuan Xuebao in 2006 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.HPLC of Formula: 6413-10-1

Study on catalytic synthesis of fructone using nanosolid superacid SO₄^2-/TiO₂ was written by Zhang, Fujuan;Wang, Shuxia. And the article was included in Xuchang Xueyuan Xuebao in 2006.HPLC of Formula: 6413-10-1 The following contents are mentioned in the article:

Fructone was prepared from Et acetoacetate and ethylene glycol using nanosolid superacid sulfated TiO₂ as catalyst. Under optimum conditions, the product yield reached 93.2%. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1HPLC of Formula: 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.HPLC of Formula: 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Varabyeva, Nastassia et al. published their research in Organic Letters in 2021 | CAS: 6413-10-1

Ti(OiPr)₄-Enabled Dual Photoredox and Nickel-Catalyzed Arylation and Alkenylation of Cyclopropanols was written by Varabyeva, Nastassia;Barysevich, Maryia;Aniskevich, Yauhen;Hurski, Alaksiej. And the article was included in Organic Letters in 2021.Name: Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate The following contents are mentioned in the article:

The Ti(OiPr)₄ additive enables this elusive cross-coupling with aryl and alkenyl bromides e.g., 4-bromoanisole leading to β-substituted ketones e.g., 1-(4-methoxyphenyl)-5-phenylpentan-3-one. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Name: Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate).

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Tan, Jason Samuel et al. published their research in Organic Letters in 2006 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 6413-10-1

Total Synthesis of Topopyrones B and D was written by Tan, Jason Samuel;Ciufolini, Marco A.. And the article was included in Organic Letters in 2006.Product Details of 6413-10-1 The following contents are mentioned in the article:

We describe a straightforward synthesis of topopyrones B and D (I, R = Cl, H, resp.), which are potent and selective inhibitors of topoisomerase I. The chem. should be suitable for addnl. structure-activity relationship (SAR) work. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Product Details of 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Astashko, Dmitry A. et al. published their research in Tetrahedron Letters in 2011 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 6413-10-1

A convenient route to 2,6-dialkyl-2,3-dihydro-4H-pyran-4-ones via oxidative cleavage of protected 1-(2-oxoalkyl)-cyclopropanols. Synthesis of (±)-hepialone and its natural congener was written by Astashko, Dmitry A.;Tyvorskii, Vladimir I.. And the article was included in Tetrahedron Letters in 2011.Product Details of 6413-10-1 The following contents are mentioned in the article:

An efficient strategy for the synthesis of 2,6-dialkyl-2,3-dihydro-4H-pyran-4-ones has been developed, the key steps of which are oxidative cleavage of the three-membered rings of 1-(2-oxoalkyl)-cyclopropanols and acid-promoted cyclization of the resulting β-hydroxyketones. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Product Details of 6413-10-1).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Product Details of 6413-10-1

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Laengle, D. et al. published their research in Chemical Communications (Cambridge, United Kingdom) in 2019 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.COA of Formula: C8H14O4

Unique photoaffinity probes to study TGFβ signaling and receptor fates was written by Laengle, D.;Wesseler, F.;Floetgen, D.;Leek, H.;Plowright, A. T.;Schade, D.. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2019.COA of Formula: C8H14O4 The following contents are mentioned in the article:

A novel synthetic approach is used to prepare a diverse set of “first-in-class” dihydropyridine-based TGFβ receptor degraders bearing photoaffinity labels. These probes serve as valuable tools to study TGFβ receptor fates and dynamics – an important challenge in chem. biol. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1COA of Formula: C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.COA of Formula: C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Li, Yonghong et al. published their research in Huagong Jishu Yu Kaifa in 2008 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Formula: C8H14O4

Synthesis of cyclohexanone glycol ketal by microwave irradiation solvent-free method catalyzed by vitamin C was written by Li, Yonghong;Li, Yueming;Hou, Jinsong. And the article was included in Huagong Jishu Yu Kaifa in 2008.Formula: C8H14O4 The following contents are mentioned in the article:

Cyclohexanone glycol ketal was synthesized using vitamin C as the catalyst by microwave irradiation solvent-free method. The effects of different conditions on yield were investigated. The result showed that the reaction time was short (3 min), the yields was high (78.8%), and it had no pollution. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Formula: C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Although benzodioxole is not particularly important, many related compounds containing the methylenedioxyphenyl group are bioactive, and thus are found in pesticides and pharmaceuticals.Formula: C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem

Long, Dan et al. published their research in European Journal of Organic Chemistry in 2022 | CAS: 6413-10-1

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C8H14O4

Enantioselective Pictet-Spengler Condensation to Access the Total Synthesis of (+)-Tabertinggine was written by Long, Dan;Zhao, Gaoyuan;Liu, Zhiqiang;Chen, Peiqi;Ma, Shiqiang;Xie, Xingang;She, Xuegong. And the article was included in European Journal of Organic Chemistry in 2022.Computed Properties of C8H14O4 The following contents are mentioned in the article:

The asym. total synthesis of iboga-type indole alkaloid (+)-tabertinggine I via chiral phosphoric acid (CPA)-catalyzed enantioselective Pictet-Spengler condensation/lactamization cascade reaction was established, which paved the way of the collective synthesis of iboga-type indole alkaloids. This study involved multiple reactions and reactants, such as Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1Computed Properties of C8H14O4).

Ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate (cas: 6413-10-1) belongs to dioxole derivatives. Dioxoles, particularly fluorinated dioxoles, are used as co-monomers to make polymers that find use in forming protective coatings for chemical resistance. Dioxole functionalized metal-organic frameworks have also been recently reported.Computed Properties of C8H14O4

Referemce:
1,3-Benzodioxole – Wikipedia,
Dioxole | C3H4O2 – PubChem